Calcium Hypochlorite MSDS
Basekim kimyasal urunler
www. basekim.com
SAFETY DATA SHEET
Version 4.6
Revision Date 05/24/2016
Print Date 06/23/2016
1. PRODUCT AND COMPANY IDENTIFICATION
1.1 Product identifiers
Product name : Calcium hypochlorite
| Product Number Brand Index-No. |
: : : |
211389 basekim kimyasal urunler 017-012-00-7 |
| CAS-No. | : | |
| 1.2 | Relevant identified uses of the substance or mixture and uses advised against | |
| Identified uses | : | Laboratory chemicals, Synthesis of substances |
| 1.3 | Details of the supplier of the safety data sheet | |
| Company | : | basekim kimyasal urunler No: 6 of Fahreddin Pasha Street, Galip Erdem Ave, Ilkbahar District Turan Gunesh Blv, Chankaya Ankara TURKEY |
| Telephone | : | 00903125147074 |
| 1.4 | Emergency telephone number | |
| Emergency Phone | : | 00903125147055 |
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Oxidizing solids (Category 2), H272
Acute toxicity, Oral (Category 4), H302
Skin corrosion (Category 1B), H314
Serious eye damage (Category 1), H318
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 GHS Label elements, including precautionary statements
Pictogram
Signal word Danger
Hazard statement(s)
H272 May intensify fire; oxidizer.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P210 Keep away from heat.
Page 2 of 8
| P220 | Keep/Store away from clothing/ combustible materials. |
| P221 | Take any precaution to avoid mixing with combustibles. |
| P260 | Do not breathe dust or mist. |
| P264 | Wash skin thoroughly after handling. |
| P270 | Do not eat, drink or smoke when using this product. |
| P273 | Avoid release to the environment. |
| P280 | Wear protective gloves/ protective clothing/ eye protection/ face protection. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. Wash contaminated clothing before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Collect spillage. |
| P301 + P312 + P330 | |
| P301 + P330 + P331 P303 + P361 + P353 |
|
| P304 + P340 + P310 | |
| P305 + P351 + P338 + P310 | |
| P363 P370 + P378 |
|
| P391 | |
| P405 | Store locked up. |
| P501 | Dispose of contents/ container to an approved waste disposal plant. |
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS
Contact with acids liberates toxic gas.
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
| Formula Molecular weight CAS-No. EC-No. Index-No. Hazardous components |
: : : : : |
CaCl2O2 142.98 g/mol 7778-54-3 231-908-7 017-012-00-7 |
| Component | Classification | Concentration |
| Calcium hypochlorite | ||
| Ox. Sol. 2; Acute Tox. 4; Skin Corr. 1B; Eye Dam. 1; Aquatic Acute 1; Aquatic Chronic 1; H272, H302, H314, H410 |
<= 100 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance .Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Continue rinsing eyes during
transport to hospital.
Page 3 of 8
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a
physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
5. FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media
Dry powder
| 5.2 | Special hazards arising from the substance or mixture No data available |
| 5.3 | Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. |
| 5.4 | Further information No data available |
6. ACCIDENTAL RELEASE MEASURES
| 6.1 | Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. |
Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment
must be avoided.
6.3 Methods and materials for containment and cleaning up
Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner or by wetbrushing and place in container for disposal according to local regulations (see section 13). Do not flush with water.
Keep in suitable, closed containers for disposal.
| 6.4 | Reference to other sections For disposal see section 13. |
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Further processing of solid materials may result
in the formation of combustible dusts. The potential for combustible dust formation should be taken into consideration
before additional processing occurs.
Provide appropriate exhaust ventilation at places where dust is formed. Keep away from sources of ignition – No
smoking. Keep away from heat and sources of ignition.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Never allow product to get in contact with water during storage. Do not store near acids.
Keep in a dry place.
Storage class (TRGS 510): Strongly oxidizing hazardous materials
| 7.3 | Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
Page 4 of 8
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
| 8.2 | Exposure controls Appropriate engineering controls |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of
workday.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove’s outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested: Dermatril® (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested: Dermatril® (KCL 740 / Aldrich Z677272, Size M)
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the
supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an
industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It
should not be construed as offering an approval for any specific use scenario.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to
the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type
N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the
sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
a) Appearance Form: powder
Colour: beige
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
Page 5 of 8
e) Melting point/freezing
point
Melting point/range: 100 °C (212 °F) – lit.
f) Initial boiling point and
boiling range
No data available
g) Flash point Not applicable
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapour pressure No data available
l) Vapour density No data available
m) Relative density 2.35 g/cm3 at 25 °C (77 °F)
n) Water solubility No data available
o) Partition coefficient: noctanol/water
No data available
p) Auto-ignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties The substance or mixture is classified as oxidizing with the category 2.
9.2 Other safety information
No data available
10. STABILITY AND REACTIVITY
10.1 Reactivity
No data available
| 10.2 | Chemical stability Stable under recommended storage conditions. |
| 10.3 | Possibility of hazardous reactions No data available |
| 10.4 | Conditions to avoid No data available |
| 10.5 | Incompatible materials Incompatible with acids., Strong reducing agents |
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. – Hydrogen chloride gas, Calcium oxide
Other decomposition products – No data available
In the event of fire: see section 5
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity
LD50 Oral – Rat – 850 mg/kg
Inhalation: No data available
Page 6 of 8
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
Hamster
fibroblast
Cytogenetic analysis
Carcinogenicity
| IARC: | 3 – Group 3: Not classifiable as to its carcinogenicity to humans (Calcium hypochlorite) 3 – Group 3: Not classifiable as to its carcinogenicity to humans (Calcium hypochlorite) No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. |
| IARC: | |
| ACGIH: | |
| NTP: |
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
| OSHA: | No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. |
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity – single exposure
No data available
Specific target organ toxicity – repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: NH3485000
12. ECOLOGICAL INFORMATION
| 12.1 | Toxicity Toxicity to fish Toxicity to daphnia and other aquatic invertebrates |
LC50 – Lepomis macrochirus – 0.057 mg/l – 96.0 h EC50 – Daphnia magna (Water flea) – 0.067 mg/l – 48 h |
12.2 Persistence and degradability
No data available
Page 7 of 8
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Very toxic to aquatic life.
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this
material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a
licensed professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
DOT (US)
UN number: 1748 Class: 5.1 Packing group: II
Proper shipping name: Calcium hypochlorite, dry
Reportable Quantity (RQ): 10 lbs
Marine pollutant:yes
Poison Inhalation Hazard: No
IMDG
| UN number: 1748 | Class: 5.1 | Packing group: II |
| Proper shipping name: CALCIUM HYPOCHLORITE, DRY | ||
| Marine pollutant:yes IATA UN number: 1748 |
Marine pollutant: yes | Class: 5.1 |
| Packing group: II |
EMS-No: F-H, S-Q
Proper shipping name: Calcium hypochlorite, dry
15. REGULATORY INFORMATION
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De
Minimis) reporting levels established by SARA Title III, Section 313.
Massachusetts Right To Know Components
Calcium hypochlorite
CAS-No.
7778-54-3
Revision Date
1993-04-24
Pennsylvania Right To Know Components
Calcium hypochlorite
CAS-No.
7778-54-3
Revision Date
1993-04-24
New Jersey Right To Know Components
Calcium hypochlorite
CAS-No.
7778-54-3
Revision Date
1993-04-24
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.
Page 8 of 8
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.
16. OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.
| Acute Tox. Aquatic Acute |
Acute toxicity Acute aquatic toxicity |
| Aquatic Chronic Eye Dam. H272 |
Chronic aquatic toxicity Serious eye damage May intensify fire; oxidizer. |
| H302 | Harmful if swallowed. |
| H314 | Causes severe skin burns and eye damage. |
| H318 | Causes serious eye damage. |
| H400 | Very toxic to aquatic life. |
| H410 | Very toxic to aquatic life with long lasting effects. |
| HMIS Rating Health hazard: |
3 |
| Chronic Health Hazard: | |
| Flammability: | 0 |
| Physical Hazard | 2 |
| NFPA Rating Health hazard: |
3 |
| Fire Hazard: | 0 |
| Reactivity Hazard: | 2 |
| Special hazard.I: | OX |