Calcium Chloride MSDS
SAFETY DATA SHEET Revision Date 20.04.2021 Version 6.2
Print Date 03.02.2023
GENERIC EU MSDS – NO COUNTRY SPECIFIC DATA – NO OEL DATA
SECTION 1: Identification of the substance/mixture and of the company/undertaking
| 1.1 | Product identifiers Product name |
: Calcium chloride |
| Product Number Brand Index-No. REACH No. CAS-No. |
: C8106 : basekim kimyasal urunler |
| : : : |
017-013-00-2 |
| 10035-04-8 |
| 1.2 | Relevant identified uses of the substance or mixture and uses advised against | |
| Identified uses | : | Laboratory chemicals, Manufacture of substances |
1.3 Details of the supplier of the safety data sheet
| Company | : | No:6 of Fahreddin Pasha Street, Galip Erdem Ave, Ilkbahar District Turan Gunesh Blv, Chankaya Ankara-TURKEY 00903125147074 |
|
| Telephone | : | ||
| Fax E-mail address Emergency telephone Emergency Phone |
: : |
00903125147055 www.basekim.com |
1.4 |
| : | 0903125147055 |
SECTION 2: Hazards identification
| 2.1 | Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 |
Eye irritation (Category 2), H319
For the full text of the H-Statements mentioned in this Section, see Section 16.
| 2.2 | Label elements Labelling according Regulation (EC) No 1272/2008 |
Pictogram
Signal word Warning
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Hazard statement(s)
| H319 Precautionary statement(s) P264 |
Causes serious eye irritation. |
| Wash skin thoroughly after handling. | |
| P280 P305 + P351 + P338 |
Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. |
| P337 + P313 |
Supplemental Hazard
Statements
none
Reduced Labeling (<= 125 ml)
Pictogram
Signal word Warning
Hazard statement(s) none
Precautionary
statement(s)
none
Supplemental Hazard
Statements
none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
SECTION 3: Composition/information on ingredients
| 3.1 | Substances | |
| Synonyms | : | Calcium chloridedihydrate |
| Formula Molecular weight CAS-No. EC-No. Index-No. |
: : : : : |
CaCl2 · 2H2O 147,01 g/mol 10035-04-8 233-140-8 017-013-00-2 |
| Component | Classification | Concentration |
| Calcium chloride dihydrate | ||
| CAS-No. EC-No. 10035-04-8 600-075-5 |
Eye Irrit. 2; H319 | <= 100 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
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SECTION 4: First aid measures
| 4.1 | Description of first-aid measures General advice |
Show this material safety data sheet to the doctor in attendance.
If inhaled
After inhalation: fresh air.
In case of skin contact
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower.
In case of eye contact
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact
lenses.
If swallowed
After swallowing: immediately make victim drink water (two glasses at most). Consult a
physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
| 4.3 | Indication of any immediate medical attention and special treatment needed No data available |
SECTION 5: Firefighting measures
| 5.1 | Extinguishing media Suitable extinguishing media |
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Unsuitable extinguishing media
For this substance/mixture no limitations of extinguishing agents are given.
5.2 Special hazards arising from the substance or mixture
Hydrogen chloride gas
Calcium oxide
Not combustible.
Ambient fire may liberate hazardous vapours.
| 5.3 | Advice for firefighters In the event of fire, wear self-contained breathing apparatus. |
5.4 Further information
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire
extinguishing water from contaminating surface water or the ground water system.
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SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact.
Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures,
consult an expert.
For personal protection see section 8.
| 6.2 | Environmental precautions Do not let product enter drains. |
6.3 Methods and materials for containment and cleaning up
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid
generation of dusts.
| 6.4 | Reference to other sections For disposal see section 13. |
SECTION 7: Handling and storage
| 7.1 | Precautions for safe handling For precautions see section 2.2. |
| 7.2 | Conditions for safe storage, including any incompatibilities Storage conditions |
Tightly closed. Dry.
| 7.3 | Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
SECTION 8: Exposure controls/personal protection
| 8.1 | Control parameters Ingredients with workplace control parameters |
8.2 Exposure controls
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Skin protection
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested:KCL 741 Dermatril® L
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This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0,11 mm
Break through time: 480 min
Material tested:KCL 741 Dermatril® L
Body Protection
protective clothing
Respiratory protection
required when dusts are generated.
Our recommendations on filtering respiratory protection are based on the following
standards: DIN EN 143, DIN 14387 and other accompanying standards relating to
the used respiratory protection system.
Recommended Filter type: Filter type P2
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
Control of environmental exposure
Do not let product enter drains.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
a) Appearance Form: crystalline
Color: white
b) Odor No data available
c) Odor Threshold No data available
d) pH 4,5 – 8,5 at 50 g/l at 20 °C
e) Melting
point/freezing point
Melting point/range: 176 °C – dec.
f) Initial boiling point
and boiling range
100 °C
g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid,
gas)
No data available
j) Upper/lower
flammability or
explosive limits
No data available
k) Vapor pressure 0,01 hPa at 20 °C
l) Vapor density No data available
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m) Relative density No data available
n) Water solubility 147 g/l at 20 °C
o) Partition coefficient:
n-octanol/water
No data available
p) Autoignition
temperature
No data available
q) Decomposition
temperature
No data available
r) Viscosity Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
No data available
10.2 Chemical stability
The product is chemically stable under standard ambient conditions (room temperature) .
10.3 Possibility of hazardous reactions
Exothermic reaction with:
boron trifluoride
vinylmethyl ether
Water
Generates dangerous gases or fumes in contact with:
Metals
Zinc
10.4 Conditions to avoid
no information available
10.5 Incompatible materials
No data available
10.6 Hazardous decomposition products
In the event of fire: see section 5
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Symptoms: After uptake of large quantities:, Stomach/intestinal disorders
Symptoms: Possible damages:, mucosal irritations
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LD50 Dermal – Rabbit – > 5.000 mg/kg
Remarks: (ECHA)
Skin corrosion/irritation
Skin – Rabbit
Result: No skin irritation
(OECD Test Guideline 404)
Remarks: (anhydrous substance)
Serious eye damage/eye irritation
Eyes – Rabbit
Result: Eye irritation
(OECD Test Guideline 405)
Remarks: (anhydrous substance)
Respiratory or skin sensitization
No data available
Germ cell mutagenicity
No data available
Test Type: Ames test
Result: negative
Remarks: (anhydrous substance)
(Lit.)
Carcinogenicity
No data available
Reproductive toxicity
No data available
Specific target organ toxicity – single exposure
No data available
Specific target organ toxicity – repeated exposure
No data available
Aspiration hazard
No data available
11.2 Additional Information
RTECS: EV9810000
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
SECTION 12: Ecological information
12.1 Toxicity
Toxicity to fish LC50 – Lepomis macrochirus (Bluegill sunfish) – 10.650 mg/l – 96 h
Remarks: (anhydrous substance)
(IUCLID)
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Toxicity to daphnia
and other aquatic
invertebrates
EC50 – Daphnia magna (Water flea) – 144 mg/l – 48 h
Remarks: (anhydrous substance)
(IUCLID)
Toxicity to algae IC50 – algae – 3.130 mg/l – 120 h
Remarks: (anhydrous substance)
(IUCLID)
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
12.6 Other adverse effects
Discharge into the environment must be avoided.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions.
SECTION 14: Transport information
14.1 UN number
| ADR/RID: – 14.2 UN proper shipping name |
IMDG: – |
| ADR/RID: Not dangerous goods | |
| IMDG: IATA: |
Not dangerous goods Not dangerous goods |
IATA: –
14.3 Transport hazard class(es)
| ADR/RID: – 14.4 Packaging group ADR/RID: – |
IMDG: – |
| IMDG: – |
IATA: –
IATA: –
14.5 Environmental hazards
| ADR/RID: no 14.6 Special precautions for user |
IMDG Marine pollutant: no |
IATA: no
Further information
Page 9 of 9
Not classified as dangerous in the meaning of transport regulations.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.
National legislation
Seveso III: Directive 2012/18/EU of the
European Parliament and of the Council on the
control of major-accident hazards involving
dangerous substances.
: Not applicable
Other regulations
Take note of Dir 94/33/EC on the protection of young people at work.
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out